Brillouin and Raman scattering spectroscopy of the liquid‐glass transition
作者:
H. Z. Cummins,
G. Li,
W. M. Du,
X. K. Chen,
N. J. Tao,
A. Sakai,
期刊:
AIP Conference Proceedings
(AIP Available online 1992)
卷期:
Volume 256,
issue 1
页码: 40-52
ISSN:0094-243X
年代: 1992
DOI:10.1063/1.42341
出版商: AIP
数据来源: AIP
摘要:
The liquid‐glass transition in calcium potassium nitrage (CKN), salol, and aqueous LiCl solution was investigated by laser light scattering spectroscopy. Combining data obtained with a Sandercock tandem Fabry Perot interferometer and a Spex tandem Raman spectrometer provided spectra spanning more than four decades in frequency. The data was analyzed to test both qualitative and quantitative predictions of the mode coupling theory of the glass transition, and produced generally excellent agreement. For CKN, we found that the MCT crossover temperature Tcis ∼378K, 45° above Tg.
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