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XIV.—On the increase in weight of molasses casks occasionally arising from absorption

 

作者: William Ferguson,  

 

期刊: Quarterly Journal of the Chemical Society of London  (RSC Available online 1854)
卷期: Volume 6, issue 2  

页码: 122-124

 

ISSN:1743-6893

 

年代: 1854

 

DOI:10.1039/QJ8540600122

 

出版商: RSC

 

数据来源: RSC

 

摘要:

MR. IV. FERGUSON ON XIV.-On the increase in Weight of Molasses casks occasionally arising from Absorption BY WILLIAM EsQ. F.C.S. FERGUSON In September 1851 attention was attracted to an unusual increase of weight in a shipment of molasses which occurred in the London Docks; it was some time before the cause could be discovered and t,he steps taken to ascertain it ended in the perfect assurance that it * Quart. Journ. Ch. SOC. I 97. Till3 INCRESSE IK WEIGHT OF MOLASSES CASKS. 123 was due to absorption. The great extent to which the action had taken place and the large amount of property in our dock warehouses which is thus proved to be occasionally affected by it lead me to be- lieve that a detailed account of this extraordinary instance may prove acceptable to the Society.For the following particulars I ani in- debted to Mr. Muggeridge of the London Docks in whose care the molasses were stored and by whom the progress of the action was watched. In August 1849 a quantity of molasses were housed for the first time in a damp cellar where they lay until September 1851 when the increase of weight was observed. In order to ascertain its amount the whole of the casks of the importation were re-weighed when it was found that every cask which had not lost a portion of its contents by breakage had gained considerably in weight. The casks were coopered and made tight and in February 1852 were again weighed when (where breakage had riot occurred) a further increase was found to have taken place.The total weight of the shipment was 1270 cwt. It was stored in 110 casks containing from 11 to 12 cwt. each. The increase on different casks varied considerably reachin 0. in some cases 38 Ibs. or about 3 per cent of the contents. The total observed increase was 23i cwt. or about 1.83 per cent. This does not represent the total real increase for it would appear that in some casks the absorbed water had just been sufficient to cover the loss from breakage but not tell as increase; and there does not seem to have been one cask which had not suffered more or less loss. The real increase of weight due to absorption must have been much greater than that shown by the weighings. Important as this result was to the merchant it was greatly exceeded by one that was after- wards observed and which was as follows.A quantity of molasses imported in large tanks were in July 1849 racked into 347 puncheons weighing about 12 cwt. each the total weight being 4160 cwt.; they were stowed in a lofty cellar where they remained till September 1852 when they were re-weighed for delivery. At various times some of the casks were found with heads bulging out from internal pressure although none of them were full when housed and it was necessary to draw off a portion to prevent them from bursting. When the bung was started the molasses rushed out with great force ascending several feet to the roof of the cellar. On re-weighing the increase was as before found to be different in different casks. On 52 there was a loss from breakage 248 had gained from 1 lb.to 30 lbs. each 67 from 30 lbs. to 40 lbs. and 20 MR. W. FERGUSON ON MOLASSES CBSICS. from 401bs. to 51 lbs. each. The total increase of weight on the shipment was 56 cwt. If we take the casks on which this incrcasc took place laying aside the 52 on which there was loss the excess of absorbed water over the leakage was about 1.6 per cent; in some of the casks it had reached as high a percentage as 4325. A third case was also observed in December 1848. 500 puncheons were filled from tanks in which they had been imported and stored in the same cellar till July 1852 when some of them were re-weighed with the same various results as to increase 5 puncheons gave the following results No.1 weight 11 3 13 lbs. gained 23 Ibs. This was the largest increase of weight though on a large number of casks it reached nearly to the same percentage. In No. 5 the excess of water absorbed over any leakage that may have occurred is 5 per cent. The bungs were at this time started and the casks which had been stored not quite full were found full to overflowing. One cask which had lost 14 Ibs. and another 9 llus. were also full We know that these casks had not been overdrawn. Now to effect a loss of 14Ibs. 4 gallons of treacle must have been replaced by water not taking into account the quantity which was required to fill the cask completely. In the case of No. 5 where the increase of weight was 68 Ibs. the quantity of water absorbed must have been very great for after supplying the loss due to leakage (ar?d all casks leak more or less) 6.8 gallons of water entered through the pores of the wood during a period of 34 years. These puncheons in which this maximum effect took place had been American meal- casks made of Quebec timber which is much more porous than the mood of which West India puncheons are usually made. The specific gravity of the freshly-imported molasses of the last lot was 1.394 and when taken in July 1852 was 1.375.

 

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