Vinyl Polymerization. 215. Decomposition of p-Methoxy-p′-nitrobenzoyl Peroxide in Monosubstituted Benzenes and Polymerization of Styrene Initiated with This Peroxide
作者:
H. Yano,
K. Shima,
K. Yamaguchi,
K. Takemoto,
M. Imoto,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1969)
卷期:
Volume 3,
issue 5
页码: 853-860
ISSN:0022-233X
年代: 1969
DOI:10.1080/10601326908051920
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The rate constant of decomposition of p-methoxy-p′-nitrobenzoyl peroxide (MN-BPO), k′d, in various monosubstituted benzenes was measured. The value of k′dseemed to increase with the polarity of the solvents. Activation energies and activation entropies of the decomposition were determined. When styrene was present, the rate constant of decomposition of MN-BPO, kd, increased markedly by three to five times, except in the case of cyano-and nitrobenzenes.
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