Exactly soluble two‐electron atomic model
作者:
R. Crandall,
R. Whitnell,
R. Bettega,
期刊:
American Journal of Physics
(AIP Available online 1984)
卷期:
Volume 52,
issue 5
页码: 438-442
ISSN:0002-9505
年代: 1984
DOI:10.1119/1.13650
出版商: American Association of Physics Teachers
关键词: hamiltonians;quantum mechanics;atomic models;expectation value;wave functions;coupling constants;helium;schroedinger equation;s states;analytical solution
数据来源: AIP
摘要:
For the class of ‘‘heliumlike’’ Hamiltonians,H=− 1/2 ∇21− 1/2 ∇22+V(r1)+V(r2)+W(r12), there is a fortuitous choice of (attractive)Vand (repulsive)Wpotentials such that the system admits of exact analytic solution in both classical and quantum pictures. Specifically, harmonic attraction and inverse‐cube repulsion forces result in a soluble three‐body problem (with infinite nuclear mass). We derive the general classical electron trajectories and give a complete set of eigenfunctions of the Hamiltonian. We indicate how exact expectation values can be obtained and show that best fits to actual helium data require a nonzero repulsive coupling constant. We exhibit ans‐state basis subset of wave functions, suitable for application to general problems of atomic and chemical physics.
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