首页   按字顺浏览 期刊浏览 卷期浏览 Infrared Studies on Alcohol-Ether Complexes in Argon Matrices
Infrared Studies on Alcohol-Ether Complexes in Argon Matrices

 

作者: W.A. P. Luck,   O. Schrems,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1980）
卷期: Volume 13, issue 10  

页码: 719-728

 

ISSN:0038-7010

 

年代: 1980

 

DOI:10.1080/00387018008064059

 

出版商: Taylor & Francis Group

 

关键词: Infrared spectra;H-bonded complexes;argon matrices

 

数据来源: Taylor

 

摘要:

The infrared spectra of CH3OH···O(CH3)2, CH3OD···O(CH3)2, C2H5OH···O(C2H5)2and C2H5OD···O(C2H5)2complexes trapped in argon matrices are reported. In dilute argon matrices the isolated 1:1 complexes of the type R2O···HOR and R2O···DOR were identified. The observed frequency shifts, Δν of the OH (OD) stretching vibrations show that the deuterium bonds are slightly stronger than the hydrogen bonds.

 

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