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Inductive Effects on Molecular Ionization Potentials. III.Primary, Secondary and Tertiary Aliphatic Amines

 

作者: Barbara W. Levitt,   L. S. Levitt,  

 

期刊: Israel Journal of Chemistry  (WILEY Available online 1971)
卷期: Volume 9, issue 1  

页码: 71-73

 

ISSN:0021-2148

 

年代: 1971

 

DOI:10.1002/ijch.197100011

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractIt is demonstrated that the ionization potentials of primary, secondary, and tertiary aliphatic amines correlate very well with the inductive and polar substituent constants, the only seriously deviating value being that for ammonia, itself. The correlation equation is found to be EI= 9.62 + 13.8 Σσ

 

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