Inductive Effects on Molecular Ionization Potentials. III.Primary, Secondary and Tertiary Aliphatic Amines
作者:
Barbara W. Levitt,
L. S. Levitt,
期刊:
Israel Journal of Chemistry
(WILEY Available online 1971)
卷期:
Volume 9,
issue 1
页码: 71-73
ISSN:0021-2148
年代: 1971
DOI:10.1002/ijch.197100011
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractIt is demonstrated that the ionization potentials of primary, secondary, and tertiary aliphatic amines correlate very well with the inductive and polar substituent constants, the only seriously deviating value being that for ammonia, itself. The correlation equation is found to be EI= 9.62 + 13.8 Σσ
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