Copolymerization of Allilidene Diacetate with Vinyl Acetate
作者:
Mitsuharu Sadamichi,
Ken Noro,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1969)
卷期:
Volume 3,
issue 5
页码: 845-852
ISSN:0022-233X
年代: 1969
DOI:10.1080/10601326908051919
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The monomer reactivity ratios for vinyl acetate (VAc)-allilidene diacetate (ADA) copolymerization have never been obtained. The composition of VAc-ADA copolymers was determined by NMR spectroscopy, measuring CH protons corresponding to ADA at 3.1τ and VAc at 5.1τ. The monomer reactivity ratios were evaluated; r1= 1.34 ± 0.05 and r2= 0.48 ± 0.03, where M1= ADA and M2= VAc. From these values the Q and e values for ADA were calculated: Q = 0.047 and e = 0.44 by taking Q = 0.026 and e = −0.22 for VAc. The H value [1] for copolymerization of ADA, VAc, and vinyl chloride (VC) is 0.87.
点击下载:
PDF (251KB)
返 回