Precision isoperibol calorimeter with automatic data acquisition and processing
作者:
C. Shin,
C. M. Criss,
期刊:
Review of Scientific Instruments
(AIP Available online 1975)
卷期:
Volume 46,
issue 8
页码: 1043-1046
ISSN:0034-6748
年代: 1975
DOI:10.1063/1.1134390
出版商: AIP
数据来源: AIP
摘要:
A precision isoperibol calorimeter with automatic data acquisition and processing, capable of operating over a wide temperature range, has been constructed and tested. The calorimeter was designed to have a very low thermal modulus and fast equilibration time. A small vapor space above the liquid and a vapor trap make the calorimeter useful for measurements with nonaqueous solvents. Time–temperature data are automatically recorded in digital form on magnetic tape and processed on a Univac 1106 computer. A series of electrical calibrations causing a temperature rise of 0.13 K were reproducible to about 0.01%. Several determinations of the enthalpy of reaction of a standard sample of Tris (hydroxymethyl) aminomethane with 0.1NHCl gave an average value of 29.764±0.013 kJ/mol, which agrees satisfactorily with published results.
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