The Dicyano [(Dithionitrito-S)Amido] Nickelate(II)Anion-A Vibrational Spectroscopy Study
作者:
D.T. Haworth,
R.S. Czernuszewicz,
期刊:
Spectroscopy Letters
(Taylor Available online 1980)
卷期:
Volume 13,
issue 11
页码: 765-776
ISSN:0038-7010
年代: 1980
DOI:10.1080/00387018008064065
出版商: Taylor & Francis Group
关键词: IR Spectra;Sulfur-Nitride Complexes;Normal Coordinate Analysis
数据来源: Taylor
摘要:
The infrared spectrum of the anion dicyano[(dithionitrito-S) amido]nickelate(II), [Ni(CN)2(S2N2H)]−has been measured from 4000 to 200 cm−1. The absorption bands have been assigned by comparison to those of Ni(CN)42and Ni(S2N2H)2. Normal coordinate analysis on the Csplanar anion [Ni(CN)2(S2N2H)]−has been carried out using molecular parameters taken from X-ray data. Band assignments for the observed frequencies in this complex are in good agreement and show an average error of less than one half of one percent. In order to obtain good agreement between calculated and observed frequencies, it was necessary to modify the Urey-Bradley force field by adding selected interaction force constants. Its electronic spectrum is also discussed.
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