Determination of the Mark-Houwink Equation Parameters and their Interrelationship
作者:
K. Wang,
H. Huang,
J. Sheng,
期刊:
Journal of Liquid Chromatography & Related Technologies
(Taylor Available online 1998)
卷期:
Volume 21,
issue 10
页码: 1457-1470
ISSN:1082-6076
年代: 1998
DOI:10.1080/10826079808000527
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This paper presents a trial and error method for determining the optimal values of k andaof the Mark-Houwink equation using polymers with different intrinsic viscosities ([η]) and molecular weight distribution (MWD) as standards. The values of k andafor polystyrene, EP-copolymer, polypropylene, polyethylene, polyvinylchloride, and polycarbonate, etc., have been determined with this method. The relative errors of the resultant [η] are below 6%, 4% or 3%. The viscosity-average molecular weight (Mv) of polystyrene standards agrees well with those of Pressure Chemical Co.; the weight- and number-average molecular weights of EP-copolymer coincide with that measured by using the low angle laser light scattering KMX-6 and the Knauer membrane osmometer, respectively. Thus, the method possesses high precision and can be applied to polymers with a wide range of molecular weight (MW) and molecular weight distribution (MWD).
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