Radiationless Energy Transfer Between Rare-Earth Ions in Solutions and its Application to the Investigation of Complexation Processes
作者:
V.L. Ermolaev,
V.P. Gruzdev,
期刊:
Spectroscopy Letters
(Taylor Available online 1978)
卷期:
Volume 11,
issue 7
页码: 537-547
ISSN:0038-7010
年代: 1978
DOI:10.1080/00387017808067775
出版商: Taylor & Francis Group
关键词: Energy transfer;rare-earth ions;complex formation
数据来源: Taylor
摘要:
Radiationless energy transfer between rare-earth ions (Ln3+) in solutions has some features: 1) the electronic transitions in Ln3+complexes causing the luminescence of energy donor and the absorption of energy acceptors are forbidden by Laporte's rule and are weakly intensive. Therefore the critical radius (Ro) of energy transfer between the rare-earth ions for dipole-dipole mechanism is close to that for exchange-resonant mechanism. This fact presents difficulties for unequivocal interpretation of the energy transfer mechanism. 2) The plus-three lanthanide ions exist in solution as a set of complexes with different number of charged ligands in the inner coordination sphere and hence with different total charge of complexes.
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