首页   按字顺浏览 期刊浏览 卷期浏览 Changes in microstructure of oriented Ba3Co2Fe24O41material during sintering. II
Changes in microstructure of oriented Ba3Co2Fe24O41material during sintering. II

 

作者: E. M. C. Huijser‐Gerits,   G. D. Rieck,  

 

期刊: Journal of Applied Crystallography  (WILEY Available online 1976)
卷期: Volume 9, issue 1  

页码: 18-27

 

ISSN:1600-5767

 

年代: 1976

 

DOI:10.1107/S002188987601042X

 

出版商: International Union of Crystallography

 

数据来源: WILEY

 

摘要:

Pellets of the ferrimagnetic material Ba3Co2Fe24O41were sintered at temperatures between 1220°C and 1310°C in (1) a non‐oriented state, (2) with a fibre texture generated by a rotating magnetic field during pressing and (3) with a fan texture due to a static magnetic field. During sintering up to 24 h. the changes in texture sharpness and density were studied. Textured samples attained a higher ultimate density than non‐oriented ones and those with fibre texture became densest. To determine the sharpnesses of the texture the maximum standardized intensities of the reflexions 0′0′0′14, 1′0′′16, 1′1′′10 and 110 were calculated from the experimental intensities. The mutual relations of the maximum standardized intensities of the four reflexions were given by representing the intensities of these reflexions for both textures as polynomials. The dependence of sharpness of texture on position in the pellet has been determined. It followed that this sharpness had to be averaged over the height of the pellet, to get a representative value for the whole pellet. Both kinds of texture were found to sharpen during normal grain growth, but during exaggerated grain growth in the last stage of sintering the sharpness of the fibre texture decreased, whereas that of the fan texture still increased. A possible explanation of this phenomenon is given on the basis of the different characters of these textures. A linear relationship is found between sharpness of texture and area porosity during normal grain growth. The compound starts decomposing at a lower temperature than

 

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