首页   按字顺浏览 期刊浏览 卷期浏览 The Method of Successive Integration: a General Technique for Recasting Kinetic Equatio...
The Method of Successive Integration: a General Technique for Recasting Kinetic Equations in a Readily Soluble Form Which Is Linear in the Coefficients and Sufficiently Rapid for Real Time Instrumental Use.

 

作者: I. B. C. Matheson,  

 

期刊: Instrumentation Science & Technology  (Taylor Available online 1987)
卷期: Volume 16, issue 3  

页码: 345-373

 

ISSN:1073-9149

 

年代: 1987

 

DOI:10.1080/10739148708543650

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Most simple chemical kinetic models which involve first or higher order processes may be transformed to be linear in their coefficients by one or moreexactintegrations of the function with respect to time. Thus, a function which is non-linear in time is converted into a function which is linear in two or more dimensions, and is readily solved using simplenumericalintegration and linear algebra. The simple cases, involving one first or second order step, yield rates which are simple functions of the determined coefficients and may be used directly. More complicated models, involving multiple exponential factors yielding rates and amplitudes which are complex functions of the determined coefficients, yield better fits after iterative improvement of the original unintegrated function. In all cases, the rates and amplitudes obtained do not differ significantly from those using the classic Levenberg-Marquardt algorithm. The method of successive integration is very fast (three to five times faster than Levenberg-Marquardt) and requires neither initial guesses nor approximation of rates and amplitudes.

 

点击下载:  PDF (841KB)



返 回