Cross-Linking of Polymers With a primary Size Distribution. II. Calculation of Size Distributions in the Sol Fraction of Nonlinear Polymers
作者:
JohnsonF. Yan,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1980)
卷期:
Volume 14,
issue 1
页码: 47-62
ISSN:0360-2559
年代: 1980
DOI:10.1080/03602558008067688
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
In a recent series of related papers [1,2], we called attention to the use of simple statistical distribution functions in the treatment of molecular size distributions of polymers. The basic distribution functions involved are the binomial, the Poisson, and the negative binomial distributions with discrete, nonzero variables. Depending on the physical conditions imposed, these distributions can be combined in a variety of ways to yield more complicated size distributions. Such combinations are exemplified by the convolution of distributions in addition polymers, the power series distribution for simple condensation polymers, the Lagrange distribution for branched polymers, etc. The most complicated case is a compound Lagrange distribution for the condensation of polymer chains with a primary size distribution [2].
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