Vibrational spectra and conformations of epifluorohydrin
作者:
V. F. Kalasinsky,
C. J. Wurrey,
期刊:
Journal of Raman Spectroscopy
(WILEY Available online 1980)
卷期:
Volume 9,
issue 1
页码: 45-49
ISSN:0377-0486
年代: 1980
DOI:10.1002/jrs.1250090111
出版商: John Wiley&Sons, Ltd.
数据来源: WILEY
摘要:
AbstractThe infrared and Raman spectra of solid, liquid and gaseous epifluorohydrin have been recorded. For the fluid phases, there are a number of spectral triplets which can be interpreted as arising from acisand two nonequivalentgaucheconformations. The number of bands which disappear as the solid sample is annealed indicates that a single conformation exists in the crystalline state. The temperature dependence of the intensities of Raman lines for the liquid state is consistent with enthalpy differences of approximately 0.6 and 0.4 kcal mol−1between the most stable and each of the less stable conformers. The existence and identities of the less stable conformers are discusse
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