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Raman Spectroscopic Studies of CH3– and CD3-(4-Tert-butylpyridine)- bis(dimethylglyoximato)cobalt (III) Complexes: Reassignment of the Methyl-Cobalt Stretching Vibration

 

作者: AngelaM. Ervin,   SaulI. Shupack,   D.Michael Byler,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1984）
卷期: Volume 17, issue 10  

页码: 603-613

 

ISSN:0038-7010

 

年代: 1984

 

DOI:10.1080/00387018408072642

 

出版商: Taylor & Francis Group

 

关键词: Methyl-Cobalt Stretching Frequency Methylcobaloxime;Methyl-d3-cobaloxime;Raman Spectroscopy.

 

数据来源: Taylor

 

摘要:

By comparing the Raman spectra of the methyl-d0- and methyl-d3-(4-tert-butylpyridine)cobaloxime1complexes, a number of bands were observed to shift due to the isotope effect. Bands appearing at 2900 cm−1In the spectrum of the lighter molecule and at 2109 cm−1in the spectrum of the C-deuterated species are assigned respectively to the axial methyl C-H and C-D symmetric stretches; the bands at 1172 and

 

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