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Far Infrared Spectroscopic Studies of Acetonitrile Vapour

 

作者: Leutloff,   E. Knözinger,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1979）
卷期: Volume 12, issue 11-12  

页码: 815-821

 

ISSN:0038-7010

 

年代: 1979

 

DOI:10.1080/00387017908069206

 

出版商: Taylor & Francis Group

 

关键词: acetonitrile;association;far-infrared.

 

数据来源: Taylor

 

摘要:

The infrared spectrum of acetonitrile vapour has been obtained in the range below 100 cm−1. There is an absorption band located at 78 cm−1which is assigned to overlapping intermolecular vibrations of dimer molecules in equilibrium with the monomer species. The equilibrium constant calculated from the pressure dependence of the band intensity amounts to 42 ± 26 1·mol−1.

 

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