The Effects of Solvents and Metal Halides upon Radical Decompositions of Alkyl α,α -Azobis-isobutyrates
作者:
Takayuki Otsu,
Bunichiro Yamada,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1969)
卷期:
Volume 3,
issue 2
页码: 187-196
ISSN:0022-233X
年代: 1969
DOI:10.1080/10601326908053804
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The radical decompositions of eight kinds of alkyl α, α′-azobisiso-butyrates in various solvents, such as cyclohexane, benzene, acetoni-trile, methanol, and acetic acid, and in methanol solution of stannic chloride or zinc chloride were investigated. It was found that the methyl α, α′-azobisisobutyrate decomposed through first-order kinetics in these solvents, but the resulting rate constants changed significantly with the kind of solvent or metal chloride used. These rate constants were also observed to correlate with the polarities and the proton-donating abilities (ETvalues) of the solvents used. The activation enthalpies and entropies at 60°C were determined; the former values were kept constant independent of the reaction medium, but the latter values were changed.
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