Infrared and Raman Spectra of Sulfur-Nitride Complexes of Nickel(II) and Palladium(II)
作者:
D.T. Haworth,
G. Lin,
期刊:
Spectroscopy Letters
(Taylor Available online 1979)
卷期:
Volume 12,
issue 6
页码: 451-465
ISSN:0038-7010
年代: 1979
DOI:10.1080/00387017908069172
出版商: Taylor & Francis Group
关键词: IR Spectra;Raman Spectra;Sulfur Nitride Complexes;Normal Coordinate Analysis
数据来源: Taylor
摘要:
The infrared and Raman spectra oftrans-Ni(S2N2CH3)2and Pd(S3N)2were measured from 4000-200 cm−1. The absorption bands were assigned by comparison to the sulfur nitride complexes of nickel(II), palladium(II) and platinum(II). Normal coordinate analyses on these complexes were carried on these data using molecular parameters taken from X-ray data. To aid in band assignments, isotope shift data ontrans-62Ni(S2N2CH3)2have also been carried out.
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