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Lineshape analysis of speed dependent collisional width inhomogeneities in CO broadened by He, N2, and Xe

 

作者: P. Duggan,   P. M. Sinclair,   A. D. May,   J. R. Drummond,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1995)
卷期: Volume 328, issue 1  

页码: 378-379

 

ISSN:0094-243X

 

年代: 1995

 

DOI:10.1063/1.47480

 

出版商: AIP

 

数据来源: AIP

 

摘要:

We present high resolution (10−4cm−1) and high signal to noise ratio (2000) infrared lineshapes of CO perturbed by Xe, N2, and He in the intermediate regime from Doppler to collision broadening. It is found that the pressure broadened component of the lineshape cannot be fit by a Lorentzian lineshape. A speed dependent collisional width is required to fit the spectra, particularly when broadened by the larger Xe perturber. Based on the theory of Robertet al. [1992], a collision broadening lineshape model is derived, and we also include the effect of Dicke narrowing.

 

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