首页   按字顺浏览 期刊浏览 卷期浏览 Synthesis and Structure Study of the Complex [Cu2(μ–C2O4) (C10H8N2)2(H2O)2] (C6H4COSO2N...
Synthesis and Structure Study of the Complex [Cu2(μ–C2O4) (C10H8N2)2(H2O)2] (C6H4COSO2N)2Crystal Structure Containing Cu (II) Bipy Oxalato and Saccharin

 

作者: Li Jianmin,   Sun Jingzhen,   Chen Pengcheng,   Wu Xintao,  

 

期刊: Crystal Research and Technology  （WILEY Available online 1995）
卷期: Volume 30, issue 3  

页码: 353-358

 

ISSN:0232-1300

 

年代: 1995

 

DOI:10.1002/crat.2170300313

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe title compound has been synthesized and its crystal structure determined at room temperature. MW = 927.86, monoclinic, space group P21/c,Z= 2,a= 9.283(1) Å,b= 16.239(2) Å,c= 12.209(1) Å, β = 99.848(9)°. The crystal structure consists of repeated [Cu2(μ–C2O4)(C10H8N2)2· (H2O)2]2cations and non‐coordinated saccharin anions. Each copper ion is in a square pyrimidal environment with two oxalate oxygen and two bipyridine nitrogen atoms as a base and one water molecule at the apex. The two copper ions are bridged by oxalato and the distance

 

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