Studies of the Polymerization of Vinyl Acetate in the Aqueous Solutions of Partially Acetylated Polyvinyl Alcohol. II. On the Change of Huggins' Constantk′ with the Variation of the Composition of the Mixed Solvent
作者:
Chen‐Chong Lin,
期刊:
Journal of the Chinese Chemical Society
(WILEY Available online 1960)
卷期:
Volume 6,
issue 2
页码: 154-159
ISSN:0009-4536
年代: 1960
DOI:10.1002/jccs.196000007
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractThe change of Huggins' constantk′ of the graft polymer solution brought about by varying the composition of the solvent was studied. The graft polymer solution studied was prepared according to the method described in the author's previous paper,(1)andk′ was obtained from viscosity measurements of the solvent with varying methanol contents. The following results were obtained:(1) The Huggings' constant was found to change with the variation in the methanol content of solvent.(2) The minimum value fork′ was attained when the solvent contained 75% methanol.(3) The first interaction coefficientsa2were determined and the critical point was also observed under the same condi
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