首页   按字顺浏览 期刊浏览 卷期浏览 Studies of the Polymerization of Vinyl Acetate in the Aqueous Solutions of Partially Ac...
Studies of the Polymerization of Vinyl Acetate in the Aqueous Solutions of Partially Acetylated Polyvinyl Alcohol. II. On the Change of Huggins' Constantk′ with the Variation of the Composition of the Mixed Solvent

 

作者: Chen‐Chong Lin,  

 

期刊: Journal of the Chinese Chemical Society  (WILEY Available online 1960)
卷期: Volume 6, issue 2  

页码: 154-159

 

ISSN:0009-4536

 

年代: 1960

 

DOI:10.1002/jccs.196000007

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe change of Huggins' constantk′ of the graft polymer solution brought about by varying the composition of the solvent was studied. The graft polymer solution studied was prepared according to the method described in the author's previous paper,(1)andk′ was obtained from viscosity measurements of the solvent with varying methanol contents. The following results were obtained:(1) The Huggings' constant was found to change with the variation in the methanol content of solvent.(2) The minimum value fork′ was attained when the solvent contained 75% methanol.(3) The first interaction coefficientsa2were determined and the critical point was also observed under the same condi

 

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