Aromaticity in heterocyclic systems. II. the application of N.M.R. in a study of the synthesis and structure of certain lmidazo[1,2‐c]pyrimidines and related pyrrolo[2,3‐d]pyrimidines
作者:
C. Wayne Noell,
Roland K. Robins,
期刊:
Journal of Heterocyclic Chemistry
(WILEY Available online 1964)
卷期:
Volume 1,
issue 1
页码: 34-41
ISSN:0022-152X
年代: 1964
DOI:10.1002/jhet.5570010108
出版商: Wiley‐Blackwell
数据来源: WILEY
摘要:
AbstractNuclear magnetic resonance spectra have been utilized in several instances to distinguish between ring closure to a derivative of imidazo[1, 2‐c]pyrimidine or pyrrolo[2, 3‐d]pyrimidine. N.m.r. studies have also been employed to select Vc as the most probable structure for 5‐methylthio‐2, 7‐imidazo[1, 2‐c]pyrimidinedione. Ultraviolet absorption spectra and n.m.r. studies in deuterium oxide support the conclusion that there is more aromaticity in the anion V g than in the neutral molecule. The present work describes several new synthetic routes to derivatives of imidazo[1,2‐c]pyrimidine and pyrrolo[2,3
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