Properties and reactions of molecules at interfaces I. Theoretical remarks on ionic concentrations in the neighbourhood of monolayers containing charged groups)
作者:
E. Havinga,
M. den Hertog‐Polak,
期刊:
Recueil des Travaux Chimiques des Pays‐Bas
(WILEY Available online 1952)
卷期:
Volume 71,
issue 1
页码: 64-71
ISSN:0165-0513
年代: 1952
DOI:10.1002/recl.19520710108
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractThe calculation of the electric potential and the ionic concentrations in the neighhourhood of a monolayer containing fatty acids or other, partially ionized, organic acids is discussed in order to get a basis for the understanding of reaction rates in unimolecular layers. The systems tinder connsideration show several features allowing straightforward theoretical reasoning. It seems difficult however to reach a detailed description without further experimental study. Therefore a simplifying treatment using the well‐knownGouy‐Chapmanmethod is deemed to he acceptable at this stage to serve as a lead in experimental resea
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