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Palladium Catalyzed Rearrangement Reaction of Linalyl Esters and Related Compounds

 

作者: S. Watanabe,   T. Fujita,   M. Sakamoto,   T. Ikeda,   T. Haga,  

 

期刊: Journal of Essential Oil Research  （Taylor Available online 1996）
卷期: Volume 8, issue 1  

页码: 29-34

 

ISSN:1041-2905

 

年代: 1996

 

DOI:10.1080/10412905.1996.9700550

 

出版商: Taylor & Francis Group

 

关键词: Linalyl acetate;geranyl acetate;PdCl2(PhCN)2;linalyl acetoacetate;geranylacetone;stereoselective rearrangement;Pd(PPh3)4

 

数据来源: Taylor

 

摘要:

Rearrangement of linalyl acetate with PdCl2(PhCN)2gave geranyl acetate as a main product(E:Z=86:14). A solution of linalyl acetoacetate in tetrahydrofuran was stirred at room temperature in the presence of Pd (PPh3)4to give geranylacetone, E: Z = 93:7.

 

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