Solvent Effect in Radical Copolymerization of Methyl Methacrylate with Styrene
作者:
Toshio Ito,
Takayuki Otsu,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1969)
卷期:
Volume 3,
issue 2
页码: 197-203
ISSN:0022-233X
年代: 1969
DOI:10.1080/10601326908053805
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A study of the copolymerization of methyl methacrylate and styrene in monosubstituted benzenes such as benzene, benzonitrile, benzyl alcohol, and phenol was made at 60°C. It was found that the copolymerization parameters changed significantly with the polarity of solvents, and the relative reactivity of methyl methacrylate toward the polystyryl radical was correlated with the ETvalues of solvents. These results and spectroscopic data suggest that in the transition state of this copolymerization the polarized structureof methyl methacrylate monomer became important, enhancing its reactivity, as the solvents became more protic.
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