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Synthesis of Nopinone from β-Pinene by Oxidative System of RuCl3-NalO4-Phase Transfer Catalyst

 

作者: Yoshlfuml Yuasa,   Haruki Tsuruta,  

 

期刊: Journal of Essential Oil Research  （Taylor Available online 1998）
卷期: Volume 10, issue 1  

页码: 39-42

 

ISSN:1041-2905

 

年代: 1998

 

DOI:10.1080/10412905.1998.9700835

 

出版商: Taylor & Francis Group

 

关键词: Nopinone;β-pinene;oxidation;ruthenium chloride;sodium periodate;phase transfer catalyst

 

数据来源: Taylor

 

摘要:

Nopinone was synthesized from β-pinene by an oxidative system of a RuCl3NalO4-phase transfer catalyst in 89% yield. Using this oxidative system, α-fencho-camphorone and camphenilone were also synthesized from α-fenchene and camphene, in 75% and 78% yield, respectively

 

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