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The Influence of the Rotation-Vibrational Interaction on the Franck-Condon Factors for Diatomic Molecules

 

作者: A.V. Stolyarov,   N.E. Kuz'Menko,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1986）
卷期: Volume 19, issue 10  

页码: 1113-1124

 

ISSN:0038-7010

 

年代: 1986

 

DOI:10.1080/00387018608069313

 

出版商: Taylor & Francis Group

 

关键词: Franck-Condon factors;diatomic molecules;rotation-vibrational interaction

 

数据来源: Taylor

 

摘要:

Using the first order perturbation theory, the analytical expressions are obtained for the dependence of the Franck-Condon factors (FCF) on the rotational quantum number J for P, Q and R-branches in the form of a polynominal expansion in J(J+1). A new quantitative criterion for estimating the influence of rotation-vibrational interactions on the FCF of diatomic molecules is obtained.

 

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