Fluorescence Behavior of Phenolic Compounds in Solutions Containing Micelles
作者:
MiriamR. de Moreno,
RobertV. Smith,
期刊:
Analytical Letters
(Taylor Available online 1983)
卷期:
Volume 16,
issue 20
页码: 1633-1645
ISSN:0003-2719
年代: 1983
DOI:10.1080/00032718308077167
出版商: Taylor & Francis Group
关键词: fluorescence;micelles;hydroxybiphenyls;apomorphine;N-n-propylnorapomorphine
数据来源: Taylor
摘要:
The effects of micelles on the fluorescence detection of phenolic compounds are described. Micelles were found to enhance the fluorescence of the drugs apomorphine (APO), and N-n-propylnorapomorphine (NPA), and a series of model hydroxybiphenyls. The fluorescence enhancements were pH dependent and biphasic behavior in hexadecyltrimethylamnonium chloride was observed for APO and NPA. Multiple equilibria and formation of zwitterions of the phenolic aporphines in the micellar environment is proposed to explain this behavior. Micellar fluorescent enhancements should be useful in improving the sensitivity of fluorometric determinations of polar compounds.
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