AN EXPERIMENTAL STUDY OF THE EFFECT OF PARAFFINIC SOLVENTS ON THE ONSET AND BULK PRECIPITATION OF ASPHALTENES
作者:
Ahmed Hammami,
Denise Chang-Yen,
JohnA. Nighswander,
Ellen Stange,
期刊:
Fuel Science and Technology International
(Taylor Available online 1995)
卷期:
Volume 13,
issue 9
页码: 1167-1184
ISSN:0884-3759
年代: 1995
DOI:10.1080/08843759508947730
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Asphaltene onset concentration and bulk deposition were measured for a typical live reservoir oil titrated withn-C6H14,n-C5H12,n-C4H10, C3H8, C2H6, CH4and CO2at 100° C (212 ° F) and 29.9 MPa (4340 psia). The concentration of titrant at asphaltene onset was observed to decrease approximately in a linear fashion with decreasing molecular weight of the paraffinic solvent; CH4did not induce any asphaltene precipitation. Bulk deposition experiments were performed using a solvent: oil volume ratio of 10:1; the results indicated that the weight percent of asphaltenes precipitated increased exponentially with decreasing molecular weight of the paraffinic solvents. More importantly, the asphaltene molecular weight showed a maximum forn-C4H10precipitated asphaltenes. Possible explanations for this unusual result are presented.
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