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AN EXPERIMENTAL STUDY OF THE EFFECT OF PARAFFINIC SOLVENTS ON THE ONSET AND BULK PRECIPITATION OF ASPHALTENES

 

作者: Ahmed Hammami,   Denise Chang-Yen,   JohnA. Nighswander,   Ellen Stange,  

 

期刊: Fuel Science and Technology International  (Taylor Available online 1995)
卷期: Volume 13, issue 9  

页码: 1167-1184

 

ISSN:0884-3759

 

年代: 1995

 

DOI:10.1080/08843759508947730

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Asphaltene onset concentration and bulk deposition were measured for a typical live reservoir oil titrated withn-C6H14,n-C5H12,n-C4H10, C3H8, C2H6, CH4and CO2at 100° C (212 ° F) and 29.9 MPa (4340 psia). The concentration of titrant at asphaltene onset was observed to decrease approximately in a linear fashion with decreasing molecular weight of the paraffinic solvent; CH4did not induce any asphaltene precipitation. Bulk deposition experiments were performed using a solvent: oil volume ratio of 10:1; the results indicated that the weight percent of asphaltenes precipitated increased exponentially with decreasing molecular weight of the paraffinic solvents. More importantly, the asphaltene molecular weight showed a maximum forn-C4H10precipitated asphaltenes. Possible explanations for this unusual result are presented.

 

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