STRUCTURAL GROUP ANALYSIS OF RESIDUES FROM ATHABASCA BITUMEN
作者:
M.R. Gray,
J.H.K. Choi,
N.O. Egiebor,
R.P. Kirchen,
E.C. Sanford,
期刊:
Fuel Science and Technology International
(Taylor Available online 1989)
卷期:
Volume 7,
issue 5-6
页码: 599-610
ISSN:0884-3759
年代: 1989
DOI:10.1080/08843758908962259
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Although the processability of bitumen from tar sand is dependent on its chemical composition, the details of this relationship are poorly understood. In this study, residue fractions from Athabasca bitumen (topped at different temperatures) and hydrocracker and coker residues were analyzed in detail. Separated class fractions were subjected to elemental analysis. NMR and IR spectroscopy, and potentiometrlc titration. These data were combined mathematically to obtain a structural profile of each oil. This analysis defines the structural changes in asphaltene precipitates due to distillation and processing, as well as the quantitative changes in the overall structural composition of the oil. Hydrocarbon structures such as paraffinic chains and naphthenes show definite trends with distillation and processing.
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