Monomer Reactivity Ratios for the Copolymerization of p-lsopropylstyrene with Styrene and Methyl Methacrylate
作者:
RichardH. Wiley,
Jung-Il Jin,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1969)
卷期:
Volume 3,
issue 5
页码: 835-843
ISSN:0022-233X
年代: 1969
DOI:10.1080/10601326908051918
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The monomer reactivity ratios for the copolymerizations of p-isopropylstyrene with styrene and with methyl methacrylate have been determined by the ionization chamber-vibrating reed electrometer radioactivity assay technique. The values from the differential form of the copolymerization equation are r1(styrene) = 1.22, r2(p-isopropylstyrene) = 0.89, and r1(methyl methacrylate) = 0.44, r2(p-isopropylstyrene) = 0.39. The values from the integrated form of the equation are r1(styrene) = 1.37 and r2= 0.99. These values indicate that, in the copolymerization of p-divinylbenzene (p-DVB) with styrene, the p-isopropylstyrene-like unit, formed from having the first vinyl group of p-DVB reacted, takes part in subsequent propagation reactions with styrene less readily than either styrene or p-DVB.
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