A detailed reaction study of phosphorus trichloride and water
作者:
G. A. Melhem,
D. Reid,
期刊:
Process Safety Progress
(WILEY Available online 1998)
卷期:
Volume 17,
issue 1
页码: 49-60
ISSN:1066-8527
年代: 1998
DOI:10.1002/prs.680170111
出版商: American Institute of Chemical Engineers
数据来源: WILEY
摘要:
AbstractThis paper reports on a comprehensive literature search and small scale experimental work on the reaction characteristics of phosphorous trichloride and water. More than 30 tests were conducted, including both closed and open test cells. The water to phosphorus trichloride molar ratio was varied from 1 to 25. When in contact, water and phosphorus trichloride will form two liquid layers with a reaction starting at the interface. The impact of variables on reaction rates including the interface surface area, layer depth, and stirring were investigated experimentally. A reaction rate model that fits all the measured data is presented. Case studies illustrating the use of this data for emergency relief systems and vent containment design are presented in reference. [1].
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