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Direct Episulfidation of Caryophyllene and Humulene

 

作者: Tatsuya Ashitani,   Shizuo Nagahama,  

 

期刊: Natural Product Letters  （Taylor Available online 1999）
卷期: Volume 13, issue 3  

页码: 163-167

 

ISSN:1057-5634

 

年代: 1999

 

DOI:10.1080/10575639908048781

 

出版商: Taylor & Francis Group

 

关键词: Episulfidation;caryophyllene;humulene;medium ring olefin

 

数据来源: Taylor

 

摘要:

Caryophyllene-6,7-episulfide (3), humulene-9,10- (4) and -6, 7-episulfide (5) found in hop oil, were prepared by heating caryophyllene or humulene with sulfur at 120°C. Examination of various types of olefins showed that this peculiar reaction occurred only to the medium ring olefins.

 

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