A Comparative Study of HCL and HBr Combustion Inhibition
作者:
ROBERTW. SCHEFER,
NANCYJ. BROWN,
期刊:
Combustion Science and Technology
(Taylor Available online 1982)
卷期:
Volume 29,
issue 3-6
页码: 113-128
ISSN:0010-2202
年代: 1982
DOI:10.1080/00102208208923593
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A modelling study of combustion inhibition in an idealized well-stirred reactor utilizing H2/O2/Ar mixtures as the reactants is presented and discussed. The effect of two chemical inhibitors, HCl and HBr, on the combustion process has been investigated at pressures of 0.01 and l.0 atmosphere over a range of equivalence ratios of 0.5 to 1.5 and inhibitor concentrations of 0 to 10 percent. Inhibitor effectiveness was determined by the competition between the radical scavenging ability of an inhibitor and the exothermicity of the scavenging reactions. For all cases considered HBr was more effective in scavenging active radicals than HCl. At 0.01 atmospheres, HCl was a more effective inhibitor in lean and stoichiometric mixtures while HBr was more effective for rich mixtures at 0.01 atmosphere and for all atmospheric pressure mixtures.
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