Broadening and shifting of the Raman Q branch in pure D2and D2‐He mixtures
作者:
P. M. Sinclair,
P. Duggan,
M. P. Le Flohic,
J. W. Forsman,
J. R. Drummond,
A. D. May,
期刊:
AIP Conference Proceedings
(AIP Available online 1995)
卷期:
Volume 328,
issue 1
页码: 380-381
ISSN:0094-243X
年代: 1995
DOI:10.1063/1.47481
出版商: AIP
数据来源: AIP
摘要:
We report the broadening and shifting of the Raman Q branch lines in D2and D2‐ He mixtures, all at 305.2 K. From a linear fit of the widths and shifts as a function of density we have determined broadening and shifting coefficients with an uncertainty of ±0.5%. None of the existing semi‐classical or quantal coefficient agree with the measurements at this level of accuracy. As well we discuss nonlinear contributions to the widths and shifts. Measurements of the broadening of the depolarized part of the Q branch in D2are reported for the first time.
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