INVESTIGATION OF THE STRUCTURE OF 1,5-METHYLENE-QUINOLIZIDINIUM ION
作者:
O. E. Edwards,
Gábor Fodor,
Léo Marion,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1966)
卷期:
Volume 44,
issue 1
页码: 13-22
ISSN:0008-4042
年代: 1966
DOI:10.1139/v66-003
出版商: NRC Research Press
数据来源: NRC
摘要:
Galinovsky observed that O-tosyllupinine (II) readily isomerized to a quaternary tosylate. Without rigorous proof he assigned to this a monomeric azetidinium salt structure. A study of the infrared and nuclear magnetic resonance spectra and molecular weight of the compound confirms the 1,5-methylene-quinolizidinium salt structure III.
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