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X-Ray Photoelectron Spectral (XPS) Studies of Molybdenum (0) and Tungsten (0) Dinitrogen Complexes

 

作者: Ragnar Larsson,   Börje Folkesson,   Abdul Malek,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1979)
卷期: Volume 12, issue 7-8  

页码: 573-578

 

ISSN:0038-7010

 

年代: 1979

 

DOI:10.1080/00387017908069180

 

出版商: Taylor & Francis Group

 

关键词: XPS;Dinitrogen Complexes;Binding Energy;Molybdenum;Tungsten;Phosphines

 

数据来源: Taylor

 

摘要:

The X-ray photoelectron spectra of M(N2)2(dppe)2, M(N2)2(PMePh2)4and M(N2)2(PMe2Ph)4; where M=W or Mo, Ph is phenyl, Me is methyl and dppe is (Ph)2P-CH2-CH2-P(Ph)2; have been investigated. The N(1s), P(2p3/2), Mo(3d5/2) and W(4f7/2) binding energies do not show significant differences between these complexes. The N(1s) signals show the separation of 1.3-1.4 eV.

 

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