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Line shapes of the fundamental vibration‐rotation‐phonon and pure rotation‐phonon spectra in HD

 

作者: R. M. Herman,   B. Weiner,   P. B. Shaw,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1995)
卷期: Volume 328, issue 1  

页码: 357-358

 

ISSN:0094-243X

 

年代: 1995

 

DOI:10.1063/1.47472

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A density matrix description of the HD vibration‐rotation‐phonon and pure rotation‐phonon spectra is presented. Because the instantaneous force on any HD molecule of interest gives both the phonon‐induced dipole and the phonon‐rotation coupling, the problem can be completely solved by using a force spectrum inferred from the corresponding phonon spectrum in D2.

 

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