Line shapes of the fundamental vibration‐rotation‐phonon and pure rotation‐phonon spectra in HD
作者:
R. M. Herman,
B. Weiner,
P. B. Shaw,
期刊:
AIP Conference Proceedings
(AIP Available online 1995)
卷期:
Volume 328,
issue 1
页码: 357-358
ISSN:0094-243X
年代: 1995
DOI:10.1063/1.47472
出版商: AIP
数据来源: AIP
摘要:
A density matrix description of the HD vibration‐rotation‐phonon and pure rotation‐phonon spectra is presented. Because the instantaneous force on any HD molecule of interest gives both the phonon‐induced dipole and the phonon‐rotation coupling, the problem can be completely solved by using a force spectrum inferred from the corresponding phonon spectrum in D2.
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