首页   按字顺浏览 期刊浏览 卷期浏览 LIQUID PHASE OXIDATION OF OCTANAL BY CUMENE HYDROPEROXIDE
LIQUID PHASE OXIDATION OF OCTANAL BY CUMENE HYDROPEROXIDE

 

作者: GeorgeW. Mushrush,   ErnaJ. Beal,   RobertE. Pellenbarg,   DennisR. Hardy,  

 

期刊: Fuel Science and Technology International  (Taylor Available online 1995)
卷期: Volume 13, issue 1  

页码: 107-123

 

ISSN:0884-3759

 

年代: 1995

 

DOI:10.1080/08843759508947667

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Reactions that lead to fuel instability can be closely linked to the presence of active oxygen species. An increasing body of evidence links oxidation reactions of hydroperoxides to the instability observed in fuels. The active oxygen compounds present in fuels are alkyl and aromatic hydroperoxides. Cumene hydroperoxide represents a logical choice for an active oxygen compound that could be present in a middle distillate fuel. This paper reports on the reactions of cumene hydroperoxide with octanal in benzene solvent at 140°C for various time periods. The complete slate of products is presented along with a suggested mechanism to explain the observed products and the implications for fuel instability reactions.

 

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