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COPROCESSING OF COAL WITH HEAVY PETROLEUM CRUDES AND RESIDUA

 

作者: ChristineW. Curtis,   JamesA. Guin,   MiloC. Pass,   KanJoe Tsai,  

 

期刊: Fuel Science and Technology International  (Taylor Available online 1987)
卷期: Volume 5, issue 3  

页码: 245-274

 

ISSN:0884-3759

 

年代: 1987

 

DOI:10.1080/08843758708915854

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

This work investigates the coprocessing of coal in six different heavy petroleum crudes and residua. Coprocessing reactions of coal and the petroleum solvents are performed under three sets of constant reaction conditions, yielding informative comparative data for processing applications. Definitive comparisons of coal reactivity and solvolysis in the petroleum solvents have been obtained using solvent fractionation which provides a measure of the degree of upgrading achieved by the liquefied coal. Regressive reactions and low coal conversions are observed in coprocessing reactions in N2at 400°C. Higher conversions and a reduction in regressive reactions are observed in H2at 400°C. Catalytic hydrotreatment and higher temperature, 425°C, result in increased coal conversion and a net production of pentane soluble materials. The amount of product fractions obtained from the upgrading of the coal alone is calculated. The effect of reaction temperature using different solvents and reaction conditions on the product slate is also examined.

 

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