A Technique for Measurement of the Heat Capacity of Metals under Pressure
作者:
G. Jura,
W. A. Stark,
期刊:
Review of Scientific Instruments
(AIP Available online 1969)
卷期:
Volume 40,
issue 5
页码: 656-660
ISSN:0034-6748
年代: 1969
DOI:10.1063/1.1684030
出版商: AIP
数据来源: AIP
摘要:
A method is described that can be used for the determination of the heat capacity of a metal (or a semiconductor) as a function of pressure and temperature. The method involves use of a dc electric pulse. If a constant currentIis passed through a wire sample of resistanceR, the heat capacityCpis related to the increase in temperature by the expressionCp=I3RR′/(dE/dt)t=0,whereR′ is the temperature derivative of the resistance, and (dE/dt)t=0is the limiting value of the time rate of change of the emf across the sample. Data are given for iron to 100 kilobars in the temperature interval from 77 to 300 K. The results obtained are in accord with earlier theoretical estimates. The Curie temperatureTcof gadolinium has also been determined from heat capacity measurements; its rate of change with pressure was found to bedTc/dP=−1.3 K/kilobar. With the equipment that is available at the present time, the measurements can be made as long as the specific resistance is 5 &mgr;&OHgr;·cm or greater.
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