Chemical Oscillations
作者:
Ulrich F. Franck,
期刊:
Angewandte Chemie International Edition in English
(WILEY Available online 1978)
卷期:
Volume 17,
issue 1
页码: 1-15
ISSN:0570-0833
年代: 1978
DOI:10.1002/anie.197800013
出版商: Hüthig&Wepf Verlag
关键词: Chemical oscillations;Oscillations
数据来源: WILEY
摘要:
AbstractUnder constant external conditions, chemical reactions may also proceed in a rhythmic manner. The kinetic mechanisms responsible for such oscillations prove to be unexpectedly complicated. It can nevertheless be demonstrated that chemical periodicity is caused by certain kinds of coupling between simultaneous reactions or transport processes. A general survey of the chemistry and phenomenology of the principal chemical oscillations is followed by a discussion of the situations leading to periodic reactions on the basis of the multivariable kinetics of feedback systems. Autocatalysis and autoinhibition play an important role, as also do kinetic instability and spatial propagation.
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