Interference between resonance and preresonance Raman scattering
作者:
M. Z. Zgierski,
期刊:
Journal of Raman Spectroscopy
(WILEY Available online 1977)
卷期:
Volume 6,
issue 1
页码: 53-56
ISSN:0377-0486
年代: 1977
DOI:10.1002/jrs.1250060111
出版商: John Wiley&Sons, Ltd.
数据来源: WILEY
摘要:
AbstractThe theory of interference effects between preresonance scattering from an intense electronic transition and resonance scattering from a forbidden electronic transition is formulated. A simple closed formula for the cross‐section of a totaliy‐symmetrical fundamental line is derived for the case where the vibrational structure of both electronic transitions is smeared out. This formula reproduces very well recently obtained experimental excitation profiles in such complex compiunds as tris (ethylenediamine) cobalt (III) chloride and tetrabromopalladate
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