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Base Induced Isomerization of γ, δ‐Epoxyketones

 

作者: Y. Gaoni,  

 

期刊: Israel Journal of Chemistry  （WILEY Available online 1971）
卷期: Volume 9, issue 1  

页码: 63-69

 

ISSN:0021-2148

 

年代: 1971

 

DOI:10.1002/ijch.197100010

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractBase treatment of open‐chain γ, δ ‐ epoxyketones yields usually two cyclopropane derivatives, a trans‐1‐acy1‐2(α ‐ hydroxyalkyl) cyclopropane (II) and a 2‐hydroxy‐3‐oxabicyclo[3, 1, 0] hexane (III). The NMR spectra and some other physical properties of compounds II and III and of some of their transformation p

 

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