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Original Uses of the Liquid Nature of the Stationary Phase in CCC. I. Extraction and Separation of Transition Metal Ions

 

作者: K. Talabardon,   M. Gagean,   J.M. Mermet,   A. Berthod,  

 

期刊: Journal of Liquid Chromatography & Related Technologies  (Taylor Available online 1998)
卷期: Volume 21, issue 1-2  

页码: 231-250

 

ISSN:1082-6076

 

年代: 1998

 

DOI:10.1080/10826079808001952

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Displacement chromatography is a way of using the chromatographic technique, in which the solutes are separated in bands in the stationary phase. Because the stationary phase is a liquid in CCC, it possible to stop the displacement process when the separated bands are still in the stationary phase. The collection of the stationary phase bands is possible. This way of using a CCC instrument was described for the separation of transition metal ions. Co2+, Ni2+, Cu2+, and Zn2+were separated using diethylhexyl phosphoric acid (DEHPA) and heptane as the stationary phase through a reversed micelle extraction process.

 

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