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Lanthanide Shift Reagents XIV Equilibrium Binding Constants for Europium Shift Reagent with Alkyl and Aryl Esters

 

作者: DavidM. Rackham,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1979)
卷期: Volume 12, issue 7-8  

页码: 567-571

 

ISSN:0038-7010

 

年代: 1979

 

DOI:10.1080/00387017908069179

 

出版商: Taylor & Francis Group

 

关键词: Europium Shift Reagent;NMR Spectra;Equilibrium Binding Constants

 

数据来源: Taylor

 

摘要:

Methods have been developed for measuring the equilibrium binding constants (K) for lanthanide shift reagents with donor substrates. Although Infrared Spectroscopy proved useful1for determining the binding of substituted anilines to the tris-tetramethylheptanedionate of Ytterbium, it was found that NMR was more sensitive and applicable to a wider range of substrates than simple alcohols and amines2,3. The NMR procedure of progressive

 

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