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The Mass Spectra of Substituted Diaryl α-Iminonitriles

 

作者: JamesG. Smith,   DouglasC. Irwin,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1979）
卷期: Volume 12, issue 10  

页码: 753-759

 

ISSN:0038-7010

 

年代: 1979

 

DOI:10.1080/00387017908069201

 

出版商: Taylor & Francis Group

 

关键词: mass spectrometry;imidoyl cyanides;α-iminonitriles

 

数据来源: Taylor

 

摘要:

The mass spectra of a series of substituted diaryl α-iminonitriles are reported. The most significant fragmentations arise from the following processes: (1) cleavage of the C-CN bond, (2) elimination of the R group from the substituted aryl ring, (3) formation of a phenyl cation (C6H5+), and (4) loss of a hydrogen atom from the parent ion. Anomolous behaviour was shown by the p-(t-butyl) derivative and reasons for this are discussed.

 

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