Kinetic Studies of the Photochemical Reduction of Uranyl Sulfate in the Presence of Alpha‐Hydroxy Iso‐Butyric Acid (I)
作者:
Kuan Pan,
Wen‐Kuei Wong,
期刊:
Journal of the Chinese Chemical Society
(WILEY Available online 1961)
卷期:
Volume 8,
issue 1‐2
页码: 1-13
ISSN:0009-4536
年代: 1961
DOI:10.1002/jccs.196100001
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractThe photochemical reduction of U(VI) to U(IV) sulfate in the presence of α‐hydroxy iso‐butyric acid, accompanied with the decarboxylation and oxidation of the acid to acetone was observed. The reaction rate was found to be of the fourth order, or of the pseudo first‐order with respect to the U(VI) ion concentration in an excess of the acid by following spectrophotometrically the concentration of U(IV) ion produced. A fourth‐order rate equation has been
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