Reactions of Dimethyl Benzoylphosphonate
作者:
I. Shahak,
J. Peretz,
期刊:
Israel Journal of Chemistry
(WILEY Available online 1971)
卷期:
Volume 9,
issue 1
页码: 35-44
ISSN:0021-2148
年代: 1971
DOI:10.1002/ijch.197100006
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractReactions of dimethyl benzoylphosphonate (I) with various nucleophiles are described. The ester can serve simply as a useful benzoylation agent or it can undergo addition reactions to give substituted α‐hydroxybenzylphosphonates. Its keto‐group can be reduced to hydroxyl and can participate in the Wittig‐Horner reaction. By the action of I with hydroxylamine in the presence of sodium formate, benzonitrile is ob
点击下载:
PDF
(836KB)
返 回